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Author(s):   Le Calve, S.; Le Bras, G.; Mellouki, A.
Title:   Kinetic studies of OH reactions with iso-propyl, iso-butyl, sec-butyl, and tert-butyl acetate
Journal:   Int. J. Chem. Kinet.
Volume:   29
Page(s):   683 - 688
Year:   1997
Reference type:   Journal article
Squib:   1997LEC/LEB683-688

Reaction:   CH3C(O)OC(CH3)3 + ·OH → Other Products + H2O
Reaction order:   2
Temperature:   253 - 372 K
Pressure:  0.13 - 0.40 bar
Rate expression:   2.23x10-12 [±3.32x10-13 cm3/molecule s] e-3284 [±756 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
253 4.67E-13
275 5.29E-13
300 5.96E-13
325 6.60E-13
350 7.20E-13
372 7.69E-13