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Accessibility information
Author(s):   Lewis, D.K.; Charney, D.J.; Kalra, B.L.; Plate, A-M.; Woodard, M.H.
Title:   Kinetics of the thermal isomerizations of gaseous vinylcyclopropane and vinylcyclobutane
Journal:   J. Phys. Chem. A
Volume:   101
Page(s):   4097 - 4102
Year:   1997
Reference type:   Journal article
Squib:   1997LEW/CHA4097-4102

Reaction:   EthenylcyclobutaneC2H4 + 1,3-Butadiene
Reaction order:   1
Temperature:   839 - 965 K
Pressure:  0.15 - 0.27 bar
Rate expression:   3.16x1014 [s-1] e-208693 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
839 3.21E1
850 4.73E1
875 1.10E2
900 2.44E2
925 5.19E2
950 1.06E3
965 1.60E3