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Author(s):   Treacy, J.; Curley, M.; Wenger, J.; Sidebottom, H.
Title:   Determination of Arrhenius parameters for the reactions of ozone with cycloalkenes
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   93
Page(s):   2877 - 2881
Year:   1997
Reference type:   Journal article
Squib:   1997TRE/CUR2877-2881

Reaction:   Cyclopentene, 1-chloro- + O3 → Products
Reaction order:   2
Temperature:   240 - 331 K
Pressure:  1.01 bar
Rate expression:   4.4x10-16 [±2.16x10-17 cm3/molecule s] e-8398 [±83.98 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Time resolution:   In real time
Analytical technique:   Chemiluminescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
240 6.54E-18
250 7.74E-18
275 1.12E-17
300 1.52E-17
325 1.97E-17
331 2.08E-17