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Accessibility information
Author(s):   Tyndall, G.S.; Orlando, J.J.; Wallington, T.J.; Dill, M.; Kaiser, E.W.
Title:   Kinetics and mechanisms of the reactions of chlorine atoms with ethane, propane, and n-butane
Journal:   Int. J. Chem. Kinet.
Volume:   29
Page(s):   43 - 55
Year:   1997
Reference type:   Journal article
Squib:   1997TYN/ORL43-55

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1997TYN/ORL43-55   C2H6 + Cl·C2H5 + HCl  298   5.75E-11           5.75E-11  2
  1997TYN/ORL43-55   C3H8 + Cl → Other Products + HCl  296   2.40              2
  Reference reaction:  C2H6 + Cl·C2H5 + HCl 2
  1997TYN/ORL43-55   C3H8 + Cl → Other Products + HCl  296   1.40E-10              2
  1997TYN/ORL43-55   C3H8 + Cl → Other Products + HCl  296   1.47              2
  Reference reaction:  C2H4 + Cl → Products 2
  1997TYN/ORL43-55   C3H8 + Cliso-C3H7 + HCl  296   0.57              2
  Reference reaction:  C3H8 + Cl → Other Products + HCl 2
  1997TYN/ORL43-55   C3H8 + Cln-C3H7 + HCl  296   0.43              2
  Reference reaction:  C3H8 + Cl → Other Products + HCl 2
  1997TYN/ORL43-55   iso-C3H7Cl + Cl → Other Products + HCl  296   2.01E-11              2
  1997TYN/ORL43-55   iso-C3H7Cl + Cl → Other Products + HCl  296   0.22              2
  Reference reaction:  C2H4 + Cl → Products 2
  1997TYN/ORL43-55   sec-C4H9Cl + Cl → Other Products + HCl  296   7.01E-11              2
  1997TYN/ORL43-55   sec-C4H9Cl + Cl → Other Products + HCl  296   0.75              2
  Reference reaction:  C2H4 + Cl → Products 2
  1997TYN/ORL43-55   n-C4H10 + Cl → Other Products + HCl  298   2.14E-10           2.14E-10  2
  1997TYN/ORL43-55   n-C4H10 + Cl → Other Products + HCl  296   3.85              2
  Reference reaction:  C2H6 + Cl·C2H5 + HCl 2
  1997TYN/ORL43-55   n-C4H10 + Cl → Other Products + HCl  297 - 299   2.00       -1522   3.70  2
  Reference reaction:  C2H6 + Cl·C2H5 + HCl 2
  1997TYN/ORL43-55   n-C4H10 + Cl → Other Products + HCl  297   2.00       -1522      2
  Reference reaction:  C2H6 + Cl·C2H5 + HCl 2
  1997TYN/ORL43-55   n-C4H10 + Cl → Other Products + HCl  296   2.19E-10              2
  1997TYN/ORL43-55   n-C4H10 + Cl → Other Products + HCl  296   2.36              2
  Reference reaction:  C2H4 + Cl → Products 2
  1997TYN/ORL43-55   n-C4H10 + Clsec-C4H9 + HCl  296   1.50E-10              2
  1997TYN/ORL43-55   n-C4H10 + Clsec-C4H9 + HCl  296   0.71              2
  Reference reaction:  n-C4H10 + Cl → Other Products + HCl 2
  1997TYN/ORL43-55   n-C4H10 + Cln-C4H9 + HCl  700   6.19E-11              2
  1997TYN/ORL43-55   n-C4H10 + Cln-C4H9 + HCl  296   0.29              2
  Reference reaction:  n-C4H10 + Cl → Other Products + HCl 2
  1997TYN/ORL43-55   n-C4H9Cl + Cl → Other Products + HCl  296   1.11E-10              2
  1997TYN/ORL43-55   n-C4H9Cl + Cl → Other Products + HCl  296   1.20              2
  Reference reaction:  C2H4 + Cl → Products 2
  1997TYN/ORL43-55   n-C3H7Cl + Cl → Other Products + HCl  296   4.80E-11              2
  1997TYN/ORL43-55   n-C3H7Cl + Cl → Other Products + HCl  296   0.52              2
  Reference reaction:  C2H4 + Cl → Products 2
  1997TYN/ORL43-55   sec-C4H9 + Cl2sec-C4H9Cl + Cl  296   2.80              2
  Reference reaction:  sec-C4H9 + O2 → C2H5CH(CH3)O2 2
  1997TYN/ORL43-55   n-C4H9 + Cl2n-C4H9Cl + Cl  296   3.10              2
  Reference reaction:  n-C4H9 + O2 → n-C4H9O2 2

Search returned 26 records.