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Author(s):   Chew, A.A.; Atkinson, R.; Aschmann, S.M.
Title:   Kinetics of the gas-phase reactions of NO3 radicals with a series of alcohols, glycol ethers, ethers and chloroalkenes
Journal:   J. Chem. Soc. Faraday Trans.
Volume:   94
Page(s):   1083 - 1089
Year:   1998
Reference type:   Journal article
Squib:   1998CHE/ATK1083-1089

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1998CHE/ATK1083-1089   1-C4H8 + NO3 → Products  298   1.25           1.25  2
  Reference reaction:  CH3CH=CH2 + NO3 → Products 2
  1998CHE/ATK1083-1089   CH2=CHCH2Cl + NO3 → Products  298   0.07           0.07  2
  Reference reaction:  CH3CH=CH2 + NO3 → Products 2
  1998CHE/ATK1083-1089   CH2=CHCH2Cl + NO3 → Products  298   5.80E-16           5.80E-16  2
  1998CHE/ATK1083-1089   CH2=CHCH2Cl + NO3 → Products  298   1.31           1.31  2
  Reference reaction:  (CH3)2CHCH(CH3)2 + NO3 → Products 2
  1998CHE/ATK1083-1089   CH3OCH2CH(CH3)OH + NO3 → Other Products + CH3COCH2OCH3  298   <1.50E-15           1.50E-15  2
  1998CHE/ATK1083-1089   CH3OCH2CH(CH3)OH + NO3 → Other Products + CH3COCH2OCH3  298   0.45           0.45  2
  Reference reaction:  Methacrolein + NO3 → Products 2
  1998CHE/ATK1083-1089   (iso-C3H7)2O + NO3 → Products  298   4.00E-15           4.00E-15  2
  1998CHE/ATK1083-1089   (iso-C3H7)2O + NO3 → Products  298   1.22           1.22  2
  Reference reaction:  Methacrolein + NO3 → Products 2
  1998CHE/ATK1083-1089   (n-C3H7)2O + NO3 → Products  298   1.64           1.64  2
  Reference reaction:  (C2H5)2O + NO3 → Products 2
  1998CHE/ATK1083-1089   (n-C3H7)2O + NO3 → Products  298   4.90E-15           4.90E-15  2
  1998CHE/ATK1083-1089   (n-C3H7)2O + NO3 → Products  298   1.49           1.49  2
  Reference reaction:  Methacrolein + NO3 → Products 2
  1998CHE/ATK1083-1089   n-C4H9OCH2CH2OH + NO3 → Products  298   <3.11E-15           3.11E-15  2
  1998CHE/ATK1083-1089   n-C4H9OCH2CH2OH + NO3 → Products  298   0.95           0.95  2
  Reference reaction:  Methacrolein + NO3 → Products 2
  1998CHE/ATK1083-1089   C2Cl4 + NO3 → Products  298   <1.79E-16           1.79E-16  2
  1998CHE/ATK1083-1089   C2Cl4 + NO3 → Products  298   0.21           0.21  2
  Reference reaction:  (CH3)2CHCH(CH3)2 + NO3 → Products 2
  1998CHE/ATK1083-1089   (Z)-CHCl=CHCl + NO3 → Products  298   1.30E-16           1.30E-16  2
  1998CHE/ATK1083-1089   (Z)-CHCl=CHCl + NO3 → Products  298   0.29           0.29  2
  Reference reaction:  (CH3)2CHCH(CH3)2 + NO3 → Products 2
  1998CHE/ATK1083-1089   CH3(CH2)2CHOH(CH2)2CH3 + NO3 → Other Products + (n-C3H7)2CO  298   <5.99E-15           5.99E-15  2
  1998CHE/ATK1083-1089   (C2H5)2O + NO3 → Products  298   3.11E-15           3.11E-15  2
  1998CHE/ATK1083-1089   (C2H5)2O + NO3 → Products  298   0.93           0.93  2
  Reference reaction:  Methacrolein + NO3 → Products 2
  1998CHE/ATK1083-1089   C2H5CH(OH)C3H7 + NO3 → Other Products + (n-C3H7)2CO  298   1.81           1.81  2
  Reference reaction:  Methacrolein + NO3 → Products 2
  1998CHE/ATK1083-1089   tert-C4H9OC2H5 + NO3 → Products  298   4.50E-15           4.50E-15  2
  1998CHE/ATK1083-1089   tert-C4H9OC2H5 + NO3 → Products  298   1.46           1.46  2
  Reference reaction:  (C2H5)2O + NO3 → Products 2
  1998CHE/ATK1083-1089   iso-C3H7OH + NO3 → Other Products + Acetone  298   <1.69E-15           1.69E-15  2
  1998CHE/ATK1083-1089   iso-C3H7OH + NO3 → Other Products + Acetone  298   0.52           0.52  2
  Reference reaction:  Methacrolein + NO3 → Products 2
  1998CHE/ATK1083-1089   n-C3H7OH + NO3 → Other Products + C2H5CHO  298   <2.09E-15           2.09E-15  2
  1998CHE/ATK1083-1089   n-C3H7OH + NO3 → Other Products + C2H5CHO  298   0.65           0.65  2
  Reference reaction:  Methacrolein + NO3 → Products 2
  1998CHE/ATK1083-1089   n-C4H9OH + NO3 → Other Products + CH3CH2CH2CHO  298   <2.71E-15           2.71E-15  2
  1998CHE/ATK1083-1089   n-C4H9OH + NO3 → Other Products + CH3CH2CH2CHO  298   0.81           0.81  2
  Reference reaction:  Methacrolein + NO3 → Products 2
  1998CHE/ATK1083-1089   CH2=CCl2 + NO3 → Products  298   1.79E-15           1.79E-15  2
  1998CHE/ATK1083-1089   CH2=CCl2 + NO3 → Products  298   4.07           4.07  2
  Reference reaction:  (CH3)2CHCH(CH3)2 + NO3 → Products 2
  1998CHE/ATK1083-1089   Methacrolein + NO3 → Products  298   0.26           0.26  2
  Reference reaction:  1-C4H8 + NO3 → Products 2
  1998CHE/ATK1083-1089   Methacrolein + NO3 → Products  298   3.30E-15           3.30E-15  2
  1998CHE/ATK1083-1089   Methacrolein + NO3 → Products  298   0.32           0.32  2
  Reference reaction:  CH3CH=CH2 + NO3 → Products 2
  1998CHE/ATK1083-1089   sec-C4H9OH + NO3 → Other Products + C2H5COCH3  298   <2.51E-15           2.51E-15  2
  1998CHE/ATK1083-1089   sec-C4H9OH + NO3 → Other Products + C2H5COCH3  298   0.75           0.75  2
  Reference reaction:  Methacrolein + NO3 → Products 2
  1998CHE/ATK1083-1089   C2HCl3 + NO3 → Products  298   3.60E-16           3.60E-16  2
  1998CHE/ATK1083-1089   C2HCl3 + NO3 → Products  298   0.82           0.82  2
  Reference reaction:  (CH3)2CHCH(CH3)2 + NO3 → Products 2

Search returned 38 records.