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Accessibility information
Author(s):   Czarnowski, J.
Title:   Kinetics and mechanism of the thermal gas-phase oxidation of tetrachloroethene by molecular oxygen in presence of trifluoromethylhypofluorite, CF3OF
Journal:   Z. Phys. Chem. (Munich)
Volume:   203
Page(s):   183 - 197
Year:   1998
Reference type:   Journal article
Squib:   1998CZA183-197

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1998CZA183-197   C2Cl4 + CF3OF → ·CCl2CFCl2 + CF3O  314 - 344   5.25E-14       6.36E04      2
  1998CZA183-197   ·CCl2CFCl2 + CF3OF → CFCl2CFCl2 + CF3O  314 - 526   6.14E-12       2.51E04      2
  1998CZA183-197   C2Cl5O → CCl3COCl + ·Cl  314 - 344   3.00E13       4.04E04      1
Search returned 3 records.