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Author(s):   Espinosa-Garcia, J.; Sanson, J.; Corchado, J.C.
Title:   The SiH4+H →’ SiH3+H2 reaction: potential energy surface, rate constants, and kinetic isotope effects
Journal:   J. Chem. Phys.
Volume:   109
Page(s):   466 - 473
Year:   1998
Reference type:   Journal article
Squib:   1998ESP/SAN466-473

Reaction:   SiH4 + H2 + SiH3
Reaction order:   2
Temperature:   200 - 1000 K
Rate expression:   9.05x10-13 [cm3/molecule s] (T/298 K)3.23 e-3581 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory
Comments:   The authors presented the rate constant in table only using erroneous units [cm3mol-1s-1]

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
200 2.90E-14
250 9.16E-14
300 2.20E-13
350 4.44E-13
400 7.98E-13
450 1.32E-12
500 2.04E-12
550 3.00E-12
600 4.24E-12
650 5.80E-12
700 7.72E-12
750 1.01E-11
800 1.28E-11
850 1.61E-11
900 1.99E-11
950 2.44E-11
1000 2.94E-11