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Author(s):   Jodkowski, J.T.; Rayez, M-T.; Rayez, J-C.; Berces, T.; Dobe, S.
Title:   Theoretical study of the kinetics of the hydrogen abstraction from methanol. 1. Reaction of methanol with fluorine atoms
Journal:   J. Phys. Chem. A
Volume:   102
Page(s):   9219 - 9229
Year:   1998
Reference type:   Journal article
Squib:   1998JOD/RAY9219-9229

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1998JOD/RAY9219-9229   CH3 + HFCH3OH + ·F  300 - 1000   1.50E-11       1.31E05      2
  1998JOD/RAY9219-9229   (·)CH2OH + HFCH3OH + ·F  300 - 1000   3.60E-12       1.65E05      2
  1998JOD/RAY9219-9229   CH3OH + ·FCH3 + HF  300 - 1000   9.97E-11   0.50          2
  1998JOD/RAY9219-9229   CH3OH + ·F(·)CH2OH + HF  300 - 1000   6.89E-11   0.27          2

Search returned 4 records.