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Accessibility information
Author(s):   Jodkowski, J.T.; Rayez, M-T.; Rayez, J-C.; Berces, T.; Dobe, S.
Title:   Theoretical study of the kinetics of the hydrogen abstraction from methanol. 1. Reaction of methanol with fluorine atoms
Journal:   J. Phys. Chem. A
Volume:   102
Page(s):   9219 - 9229
Year:   1998
Reference type:   Journal article
Squib:   1998JOD/RAY9219-9229

Reaction:   (·)CH2OH + HFCH3OH + ·F
Reaction order:   2
Temperature:   300 - 1000 K
Rate expression:   3.6x10-12 [cm3/molecule s] e-165125 [J/mole]/RT
Category:  Theory
Data type:   Ab initio

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 6.40E-41
350 8.19E-37
400 9.85E-34
450 2.45E-31
500 2.02E-29
550 7.49E-28
600 1.52E-26
650 1.94E-25
700 1.72E-24
750 1.14E-23
800 5.96E-23
850 2.57E-22
900 9.39E-22
950 3.00E-21
1000 8.54E-21