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Accessibility information
Author(s):   Laskin, A.; Lifshitz, A.
Title:   Thermal decomposition of quinoline and isoquinoline. The role of 1-indene imine radical
Journal:   J. Phys. Chem. A
Volume:   102
Page(s):   928 - 946
Year:   1998
Reference type:   Journal article
Squib:   1998LAS/LIF928-946

Reaction:   Quinoline → Products
Reaction order:   1
Temperature:   1280 - 1700 K
Pressure:  0.93 bar
Rate expression:   1.0x1013 [s-1] e-315950 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1280 1.28E0
1300 2.02E0
1325 3.51E0
1350 5.96E0
1375 9.95E0
1400 1.63E1
1425 2.62E1
1450 4.15E1
1475 6.48E1
1500 9.95E1
1525 1.51E2
1550 2.25E2
1575 3.32E2
1600 4.85E2
1625 6.99E2
1650 9.96E2
1675 1.40E3
1700 1.96E3