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Accessibility information
Author(s):   Lifshitz, A.; Tamburu, C.
Title:   Thermal decomposition of acetonitrile. Kinetic modeling
Journal:   Int. J. Chem. Kinet.
Volume:   30
Page(s):   341 - 347
Year:   1998
Reference type:   Journal article
Squib:   1998LIF/TAM341-347

Reaction:   N=C-CH2CH2CH2CHCN +
Reaction order:   1
Temperature:   1350 - 1950 K
Rate expression:   3.0x1013 [s-1] e-167360 [J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1350 1.00E7
1400 1.71E7
1450 2.81E7
1500 4.46E7
1550 6.87E7
1600 1.03E8
1650 1.51E8
1700 2.16E8
1750 3.03E8
1800 4.17E8
1850 5.65E8
1900 7.52E8
1950 9.87E8