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Accessibility information
Author(s):   Piety, C.A.; Soller, R.; Nicovich, J.M.; McKee, M.L.; Wine, P.H.
Title:   Kinetic and mechanistic study of the reaction of atomic chlorine with methyl bromide over an extended temperature range
Journal:   Chem. Phys.
Volume:   231
Page(s):   155 - 169
Year:   1998
Reference type:   Journal article
Squib:   1998PIE/SOL155-169

Reaction:   CH3Br + ClHCl + ·CH2Br
Reaction order:   2
Temperature:   213 - 697 K
Pressure:  2.67E-2 - 0.33 bar
Rate expression:   3.32x10-12 [cm3/molecule s] (T/298 K)1.42 e-5030 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Resonance fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
213 1.20E-13
225 1.51E-13
250 2.30E-13
275 3.28E-13
300 4.46E-13
325 5.84E-13
350 7.41E-13
375 9.17E-13
400 1.11E-12
425 1.32E-12
450 1.55E-12
475 1.80E-12
500 2.07E-12
525 2.34E-12
550 2.64E-12
575 2.95E-12
600 3.27E-12
625 3.61E-12
650 3.96E-12
675 4.33E-12
697 4.66E-12