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Accessibility information
Author(s):   Sommer, T.; Roth, P.
Title:   High-temperature reactions of fullerene C60 with H and OH
Journal:   J. Phys. Chem. A
Volume:   102
Page(s):   3083 - 3088
Year:   1998
Reference type:   Journal article
Squib:   1998SOM/ROT3083-3088

Reaction:   ·OH + [5,6]-Fullerene-C60 → Products
Reaction order:   2
Temperature:   2020 - 2540 K
Pressure:  1.30 bar
Rate expression:   1.66x10-9 [cm3/molecule s] e-50136 [J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Shock tube
Time resolution:   In real time
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
2020 8.39E-11
2050 8.77E-11
2100 9.40E-11
2150 1.01E-10
2200 1.07E-10
2250 1.14E-10
2300 1.21E-10
2350 1.28E-10
2400 1.35E-10
2450 1.42E-10
2500 1.49E-10
2540 1.55E-10