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Accessibility information
Author(s):   Tsang, W.; Lifshitz, A.
Title:   Kinetic stability of 1,1,1-trifluoroethane
Journal:   Int. J. Chem. Kinet.
Volume:   30
Page(s):   621 - 628
Year:   1998
Reference type:   Journal article
Squib:   1998TSA/LIF621-628

Reaction:   CH3CF3CH2=CF2 + HF
Reaction order:   1
Reference reaction:   tert-C4H9OHiso-C4H8 + H2O
Temperature:   1050 - 1200 K
Pressure:  2.53 bar
Rate expression:   7.0x1014 [s-1] e-310130 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Time resolution:   In both real time and by end product analysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1050 2.61E-1
1075 5.97E-1
1100 1.31E0
1125 2.79E0
1150 5.74E0
1175 1.14E1
1200 2.22E1