Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Ysang, W.; Lifshitz, A.
Title:   Kinetic stability of 1,1,1-trifluoroethane
Journal:   Int. J. Chem. Kinet.
Volume:   30
Page(s):   621 - 628
Year:   1998
Reference type:   Journal article
Squib:   1998YSA/LIF621-628

Reaction:   CH3CF3CH2=CF2 + HF
Reaction order:   1
Temperature:   1050 - 1200 K
Rate expression:   3.0x1015 [±1.0x1015 s-1] e-320523 [±2910 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is high pressure limit
Experimental procedure:   Shock tube
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1050 3.41E-1
1075 8.00E-1
1100 1.81E0
1125 3.94E0
1150 8.29E0
1175 1.69E1
1200 3.35E1