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Accessibility information
Author(s):   Bedjanian, Y.; Le Bras, G.; Poulet, G.
Title:   Kinetic Study of the Reactions of Br2 with OH and OD
Journal:   Int J. Chem. Kinet.
Volume:   31
Page(s):   698 - 704
Year:   1999
Reference type:   Journal article
Squib:   1999BED/LEB698-704

Reaction:   ·OH + Br2Br· + HOBr
Reaction order:   2
Temperature:   230 - 360 K
Pressure:  1.33E-3 bar
Rate expression:   1.8x10-11 [±3.0x10-1 cm3/molecule s] e1954 [±416 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Electron beam
Time resolution:   In real time
Analytical technique:   Mass spectrometry
Comments:   The rate constant agrees well with previous measurements.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
230 5.00E-11
250 4.61E-11
275 4.23E-11
300 3.94E-11
325 3.71E-11
350 3.52E-11
360 3.46E-11