Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Campbell, M.L.
Title:   Temperature Dependent Rate Constants for the Reactions of Gas Phase Lanthanides with CO2
Journal:   Phys. Chem. Chem. Phys.
Volume:   1
Page(s):   3731 - 3735
Year:   1999
Reference type:   Journal article
Squib:   1999CAM3731-3735

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1999CAM3731-3735   CO2 + Ce → Products  348 - 498   3.40E-10       3500      2
  1999CAM3731-3735   CO2 + Pr → Products  348 - 573   2.50E-10       7900      2
  1999CAM3731-3735   CO2 + Nd → Products  298 - 623   3.30E-10       1.20E04   2.60E-12  2
  1999CAM3731-3735   CO2 + Sm → Products  373 - 573   1.70E-10       1.58E04      2
  1999CAM3731-3735   CO2 + Eu → Products  373 - 623   6.60E-10       3.92E04      2
  1999CAM3731-3735   CO2 + Gd → Products  348 - 523   1.10E-10       5800      2
  1999CAM3731-3735   CO2 + Tb → Products  298 - 623   1.10E-10       1.08E04   1.41E-12  2
  1999CAM3731-3735   CO2 + Dy → Products  298 - 598   4.00E-10       3.03E04   1.95E-15  2
  1999CAM3731-3735   CO2 + Ho → Products  348 - 623   3.70E-10       3.31E04      2
  1999CAM3731-3735   CO2 + Er → Products  348 - 623   5.80E-10       3.69E04      2
  1999CAM3731-3735   CO2 + Tm → Products  498 - 623   1.10E-10       4.54E04      2

Search returned 11 records.