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Author(s):   Chen, C.-J.; Bozzelli, J.W.
Title:   Analysis of Tertiary Butyl Radical + O2, Isobutene + HO2, Isobutene + OH, and Isobutene-OH Adducts + O2: A Detailed Tertiary Butyl Oxidation Mechanism
Journal:   J. Phys. Chem. A
Volume:   103
Page(s):   9731 - 9769
Year:   1999
Reference type:   Journal article
Squib:   1999CHE/BOZ9731-9769

Reaction:   (CH3)3CO2tert-C4H9 + O2
Reaction order:   1
Temperature:   300 - 2000 K
Rate expression:   6.83x1015 [s-1] e-140164 [J/mole]/RT
Category:  Experiment
Data type:   RRK(M) extrapolation
Pressure dependence:   Rate constant is high pressure limit

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
300 2.69E-9
400 3.40E-3
500 1.56E1
600 4.29E3
700 2.37E5
800 4.82E6
900 5.01E7
1000 3.26E8
1100 1.51E9
1200 5.41E9
1300 1.59E10
1400 4.03E10
1500 8.99E10
1600 1.81E11
1700 3.37E11
1800 5.85E11
1900 9.57E11
2000 1.49E12