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Author(s):   Chuchani, G.; Rotinov, A.; Dominguez, R.M.
Title:   The kinetics and mechanisms of gas phase elimination of primary, secondary, and tertiary 2-hydroxyalkylbenzenes
Journal:   Int. J. Chem. Kinet.
Volume:   31
Page(s):   401 - 407
Year:   1999
Reference type:   Journal article
Squib:   1999CHU/ROT401-407

Reaction:   2-methyl-1-phenyl-2-propanol → Other Products + H2O
Reaction order:   1
Temperature:   722 - 764 K
Rate expression:   1.9x1012 [s-1] e-226200 [J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Thermal
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Reactor surface seasoned with allyl bromide.No effect of change in surface to volume by factor of 6.Pressure decrease of substrate followed. Gas chromatography used for products."Other Products" are the mixed phenylpropenes.

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
722 8.40E-5
725 9.59E-5
750 3.35E-4
764 6.44E-4