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Accessibility information
Author(s):   Dagaut, P.; Lecomte, F.; Chevailler, S.; Cathonnet, M.
Title:   Experimental and Kinetic Modeling of Nitric Oxide Reduction by Acetylene in an Atmospheric Pressure Jet-Stirred Reactor
Journal:   Fuel
Volume:   78
Page(s):   1245 - 1252
Year:   1999
Reference type:   Journal article
Squib:   1999DAG/LEC1245-1252

Reaction:   NO + HCCOCO + HC-N=O
Reaction order:   2
Temperature:   1050 - 1300 K
Pressure:  1.01 bar
Rate expression:   6.38x10-11 [cm3/molecule s] e-1824 [J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Experimental procedure:   Stirred flow reactor(PSR etc.)
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1050 5.17E-11
1075 5.20E-11
1100 5.22E-11
1125 5.25E-11
1150 5.27E-11
1175 5.29E-11
1200 5.31E-11
1225 5.33E-11
1250 5.35E-11
1275 5.37E-11
1300 5.39E-11