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Accessibility information
Author(s):   DeMore, W.B.; Bayes, K.D.
Title:   Rate constants for the reactions of hydroxyl radical with several alkanes, cycloakanes, and dimethyl ether
Journal:   J. Phys. Chem. A
Volume:   103
Page(s):   2649 - 2654
Year:   1999
Reference type:   Journal article
Squib:   1999DEM/BAY2649-2654

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1999DEM/BAY2649-2654   1-C4H10 + ·OH → Other Products + H2O  235 - 361   1.68E-11       4856   2.36E-12  2
  1999DEM/BAY2649-2654   n-C5H12 + ·OH → Other Products + H2O  233 - 364   1.94E-11       4107   3.70E-12  2
  1999DEM/BAY2649-2654   1-C6H14 + ·OH → Other Products + H2O  292 - 367   2.61E-11       3991   5.21E-12  2
  1999DEM/BAY2649-2654   Cyclohexane + ·OHCyclohexyl + H2O  298 - 368   3.59E-11       4157   6.70E-12  2
  1999DEM/BAY2649-2654   (CH3)2O + ·OHH2O + CH3OCH2  263 - 361   1.51E-11       4124   2.86E-12  2
  1999DEM/BAY2649-2654   Cyclobutane + ·OHCyclobutyl + H2O  298 - 368   1.63E-11       5080   2.10E-12  2
  1999DEM/BAY2649-2654   Cyclopentane + ·OHCyclopentyl + H2O  273 - 423   2.57E-11       4141   4.84E-12  2
  1999DEM/BAY2649-2654   C3H8 + ·OH → Other Products + H2O  227 - 428   1.29E-11       6070   1.11E-12  2
  1999DEM/BAY2649-2654   Cyclopropane + ·OHCyclopropyl + H2O  273 - 423   5.15E-12       1.05E04   7.50E-14  2

Search returned 9 records.