Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Fahr, A.; Laufer, A.H.; Tardy, D.C.
Title:   Pressure Effect on CH3 and C2H3 Cross-Radical Reactions
Journal:   J. Phys. Chem. A
Volume:   103
Page(s):   8433 - 8439
Year:   1999
Reference type:   Journal article
Squib:   1999FAH/LAU8433-8439

Reaction:   ·CH3 + C2H3CH4 + C2H2
Reaction order:   2
Temperature:   298 K
Pressure:  2.80E-3 - 0.27 bar
Rate expression:   3.3x10-11 [cm3/molecule s]
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Gas chromatography

View full bibliographic record.