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Author(s):   Frank, A.J.; Turecek, F.
Title:   Methylsulfonyl and Methoxysulfinyl Radicals and Cations in the Gas Phase. A Variable-Time and Photoexcitation Neutralization-Reionization Mass Spectrometric and ab Initio/RRKM Study
Journal:   J. Phys. Chem. A
Volume:   103
Page(s):   5348 - 5361
Year:   1999
Reference type:   Journal article
Squib:   1999FRA/TUR5348-5361

Reaction:   ·CH3 + SO2 → CH3S(O)2
Reaction order:   2
Temperature:   298 K
Rate expression:   2.86x10-13 [cm3/molecule s]
Category:  Experiment
Data type:   RRK(M) extrapolation
Comments:   The rate constant is consistent with 1973JAM/KER2124, but higher than 72SID/BAD72.

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