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Author(s):   Goumri, A.; Rocha, J.-D. R.; Laakso, D.; Smith, C.E.; Marshall, P.
Title:   Characterization of Reaction Pathways on the Potential Energy Surfaces for H + SO2 and HS + O2
Journal:   J. Phys. Chem. A
Volume:   103
Page(s):   11328 - 11335
Year:   1999
Reference type:   Journal article
Squib:   1999GOU/ROC11328-11335

Reaction:   HSO2SO2 +
Reaction order:   1
Temperature:   200 - 2000 K
Rate expression:   3.42x1013 [s-1] (T/298 K)0.90 e-76826 [J/mole]/RT
Category:  Theory
Data type:   RRK(M) extrapolation
Pressure dependence:   Rate constant is high pressure limit

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
200 2.06E-7
300 1.45E0
400 4.14E3
500 5.14E5
600 1.32E7
700 1.37E8
800 8.02E8
900 3.22E9
1000 9.88E9
1100 2.49E10
1200 5.43E10
1300 1.05E11
1400 1.87E11
1500 3.10E11
1600 4.82E11
1700 7.15E11
1800 1.02E12
1900 1.40E12
2000 1.87E12