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Accessibility information
Author(s):   Hynes, R.G.; Mackie, J.C.; Masri, A.R.
Title:   Shock-tube study of the pyrolysis of the halon replacement molecule CF3CHFCF3
Journal:   J. Phys. Chem. A
Volume:   103
Page(s):   54 - 61
Year:   1999
Reference type:   Journal article
Squib:   1999HYN/MAC54-61

Reaction:   CF3CHFCF3 + ·F(CF3)2CF + HF
Reaction order:   2
Temperature:   1200 - 1500 K
Pressure:  16.27 - 18.27 bar
Rate expression:   6.61x10-11 [cm3/molecule s] e-10061 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1200 2.41E-11
1225 2.46E-11
1250 2.51E-11
1275 2.56E-11
1300 2.61E-11
1325 2.65E-11
1350 2.70E-11
1375 2.74E-11
1400 2.78E-11
1425 2.83E-11
1450 2.87E-11
1475 2.91E-11
1500 2.95E-11