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Author(s):   Krasnoperov, L.N.; Mehta, K.
Title:   Kinetic Study of CH3 + HBr and CH3 + Br Reactions by Laser Photolysis - Transient Absorption Over 1-100 Bar Pressure Range
Journal:   J. Phys. Chem. A
Volume:   103
Page(s):   8008 - 8020
Year:   1999
Reference type:   Journal article
Squib:   1999KRA/MEH8008-8020

Reaction:   ·CH3 + Br·CH3Br
Reaction order:   2
Reference reaction order:   2
Temperature:   297 K
Pressure:  11.20 bar
Rate expression:   1.15±3.0x10-1
Category:  Experiment
Data type:   Relative rate value measured
Pressure dependence:   Rate constant is pressure dependent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   direct abstraction, 81%, main channel

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