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Accessibility information
Author(s):   Maity, D.K.; Duncan, W.T.; Truong, T.N.
Title:   Direct ab initio dynamics studies of the hydrogen abstraction reactions of hydrogen atom with fluoromethanes
Journal:   J. Phys. Chem. A
Volume:   103
Page(s):   2152 - 2159
Year:   1999
Reference type:   Journal article
Squib:   1999MAI/DUN2152-2159

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1999MAI/DUN2152-2159   H2 + ·CH3CH4 +   200 - 1000   2.51E-13       3.50E04   1.84E-19  2
  1999MAI/DUN2152-2159   H2 + ·CF3CHF3 +   200 - 1000   2.09E-13       2.59E04   6.14E-18  2
  1999MAI/DUN2152-2159   H2 + ·CHF2CH2F2 +   200 - 1000   1.79E-13       3.68E04   6.27E-20  2
  1999MAI/DUN2152-2159   H2 + ·CH2FCH3F +   200 - 1000   1.53E-13       4.15E04   8.16E-21  2
  1999MAI/DUN2152-2159   CH3F + H2 + ·CH2F  200 - 1000   6.33E-12       2.78E04   8.58E-17  2
  1999MAI/DUN2152-2159   CH4 + H2 + ·CH3  200 - 1000   7.34E-12       3.67E04   2.75E-18  2
  1999MAI/DUN2152-2159   CH2F2 + H2 + ·CHF2  200 - 1000   4.47E-12       2.63E04   1.11E-16  2
  1999MAI/DUN2152-2159   CHF3 + H2 + ·CF3  200 - 1000   2.94E-12       3.79E04   6.65E-19  2

Search returned 8 records.