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Author(s):   Martinez, E.; Cabanas, B.; Aranda, A.; Martin, P.; Salgado, S.
Title:   Absolute Rate Coefficients for the Gas-Phase Reactions of NO3 Radical with a Series of Monoterpenes at T = 298 to 433 K
Journal:   J. Atmos. Chem.
Volume:   33
Page(s):   265 - 282
Year:   1999
Reference type:   Journal article
Squib:   1999MAR/CAB265-282

Reaction:   d-Limonene + NO3 → Products
Reaction order:   2
Temperature:   298 K
Pressure:  1.33E-3 bar
Rate expression:   9.4x10-12 [±9.0x10-13 cm3/molecule s]
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Electron beam
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   NO3 generated by reaction of F with HNO3.Rate constant at 433 K = (5.8+/-0.7) x E-12 cm3 molec-1 s-1

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