Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Martinez, E.; Cabanas, B.; Aranda, A.; Martin, P.; Salgado, S.
Title:   Absolute Rate Coefficients for the Gas-Phase Reactions of NO3 Radical with a Series of Monoterpenes at T = 298 to 433 K
Journal:   J. Atmos. Chem.
Volume:   33
Page(s):   265 - 282
Year:   1999
Reference type:   Journal article
Squib:   1999MAR/CAB265-282

Reaction:   d-Limonene + NO3 → Products
Reaction order:   2
Temperature:   298 K
Pressure:  1.33E-3 bar
Rate expression:   9.4x10-12 [±9.0x10-13 cm3/molecule s]
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Electron beam
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   NO3 generated by reaction of F with HNO3.Rate constant at 433 K = (5.8+/-0.7) x E-12 cm3 molec-1 s-1

View full bibliographic record.