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Accessibility information
Author(s):   Marinov, N.M.
Title:   A detailed chemical kinetic model for high temperature ethanol oxidation
Journal:   Int. J. Chem. Kinet.
Volume:   31
Page(s):   183 - 220
Year:   1999
Reference type:   Journal article
Squib:   1999MAR183-220

Reaction:   O2 + HCCO → Products
Reaction order:   2
Temperature:   300 - 1500 K
Rate expression:   3.99x10-13 [cm3/molecule s] e3573 [J/mole]/RT
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other
Comments:   Estimated temperature dependence at higher temperatures consistent with lower temperature measurements. Assumed products CO2 + HCO. (HCO then decomposes to CO+H)

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 1.67E-12
400 1.17E-12
500 9.41E-13
600 8.16E-13
700 7.36E-13
800 6.82E-13
900 6.42E-13
1000 6.12E-13
1100 5.89E-13
1200 5.70E-13
1300 5.55E-13
1400 5.42E-13
1500 5.31E-13