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Author(s):   Maurer, T.; Hass, H.; Barnes, I.; Becker, K.H.
Title:   Kinetic and Product Study of the Atmospheric Photooxidation of 1,4-Dioxane and Its Main Reaction Product Ethylene Glycol Diformate
Journal:   J. Phys. Chem. A
Volume:   103
Page(s):   5032 - 5039
Year:   1999
Reference type:   Journal article
Squib:   1999MAU/HAS5032-5039

Reaction:   ethylene glycol diformate + ·OH → Products
Reaction order:   2
Temperature:   298 K
Pressure:  1.00 bar
Rate expression:   4.72x10-13 [±3.1x10-1 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   This rate constant is the first determination.

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