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Author(s):   McClean, R.E.; Campbell, M.L.; Vorce, M.D.; Medhurst, L.J.
Title:   Association reactions of manganese, iron, and ruthenium with nitric oxide
Journal:   J. Phys. Chem. A
Volume:   103
Page(s):   2659 - 2663
Year:   1999
Reference type:   Journal article
Squib:   1999MCC/CAM2659-2663

Reaction:   C2H4 + Fe → Products
Reaction order:   2
Temperature:   622 K
Pressure:  2.67E-2 - 0.93 bar
Rate expression:   4.4x10-13 [±1.1x10-13 cm3/molecule s]
Bath gas:   N2
Category:  Experiment
Data type:   High or low pressure extrapolation
Pressure dependence:   Rate constant is high pressure limit
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   248 nm photolysis of ferrocene. LIF detection of Fe 271.994, 344.061 nm excitation. RRKM extrapolation to high pressure limit.

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