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Author(s):   Neeb, P.; Moortgat, G.K.
Title:   Formation of OH Radicals in the Gas-Phase Reaction of Propene, Isobutene and Isoprene with O3: Yields and Mechanistic Implications
Journal:   J. Phys. Chem. A
Volume:   103
Page(s):   9003 - 9012
Year:   1999
Reference type:   Journal article
Squib:   1999NEE/MOO9003-9012

Reaction:   CH2=C(CH3)CH=CH2 + O3 → Other Products + ·OH
Reaction order:   2
Reference reaction:   CH2=C(CH3)CH=CH2 + O3 → Products
Reference reaction order:   2
Temperature:   298 K
Pressure:  0.97 bar
Rate expression:   2.6x10-1±6.0x10-2
Category:  Experiment
Data type:   Relative rate value measured
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   Determined from decrease of effective rate constant upon addition of cyclohexane.

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