Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Orlando, J.J.; Tyndall, G.S.
Title:   Mechanism of the OH-Initiated Oxidation of Methacrolein
Journal:   Geophys. Res. Lett.
Volume:   26
Page(s):   2191 - 2194
Year:   1999
Reference type:   Journal article
Squib:   1999ORL/TYN2191-2194

Reaction:   Methacrolein + ·OH → CH2(OH)C(CH3)CHO
Reaction order:   2
Reference reaction order:   2
Temperature:   298 K
Pressure:  0.93 - 1.00 bar
Rate expression:   5.5x10-1
Category:  Experiment
Data type:   Relative rate value measured
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Fourier transform (FTIR)
Comments:   The attack of OH on CH2=C(CH3)CHO occurs 55% via addition to the double bond, the other possible product is CH2C(OH)(CH3)CHO.

View full bibliographic record.