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Author(s):   Roden, P.J.; Stark, M.S.; Waddington, D.J.
Title:   The reaction of acrolein with acetylperoxyl radicals in the gas-phase
Journal:   Int. J. Chem. Kinet.
Volume:   31
Page(s):   277 - 282
Year:   1999
Reference type:   Journal article
Squib:   1999ROD/STA277-282

Reaction:   CH2=CHCHO + CH3C(O)OO(·)CH3C(O)CHO + CO2 + ·CH3
Reaction order:   2
Temperature:   383 K
Pressure:  0.40 bar
Rate expression:   2.16x10-17 [±1.49x10-17 cm3/molecule s]
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Mass spectrometry

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