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Author(s):   Teruel, M.A.; Taccone, R.A.; Lane, S.I.
Title:   Discharge Flow-Chemiluminescence Study of the Rate Coefficients for O(3P) + CF2 = CCl2 and O(3P) + CF3CF = CF2 Reactions at 298 K
Journal:   Int J. Chem. Kinet.
Volume:   31
Page(s):   867 - 872
Year:   1999
Reference type:   Journal article
Squib:   1999TER/TAC867-872

Reaction:   CF3CF=CF2 + → Products
Reaction order:   2
Temperature:   298 K
Pressure:  4.27E-3 bar
Rate expression:   3.0x10-14 [±6.0x10-1 cm3/molecule s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Electron beam
Time resolution:   In real time
Analytical technique:   Chemiluminescence
Comments:   The rate constant is closeto the values from 1987CVE261 and 1966SAU/HEI1950-1958 and 1965SAU/HEI4062-4068.

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