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Author(s):   Aschmann, S.M.; Arey, J.; Atkinson, R.
Title:   Atmospheric Chemistry of Selected Hydroxycarbonyls
Journal:   J. Phys. Chem. A
Volume:   104
Page(s):   3998 - 4003
Year:   2000
Reference type:   Journal article
Squib:   2000ASC/ARE3998-4003

Reaction:   CH3C(O)CH(CH3)CH2OH + ·OH → Products
Reaction order:   2
Reference reaction:   n-C8H18 + ·OH → Products
Temperature:   296 K
Pressure:  0.99 bar
Rate expression:   1.62x10-11 [±3.4x10-12 cm3/molecule s]
Bath gas:   Air
Category:  Experiment
Data type:   Relative value normalized by a reference value
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Gas chromatography
Comments:   A 7900 L Teflon chamber with GC-FID detection system.

Placed on an absolute basis by use of a rate constant of OH + n-octane: 8.67E-12 cm3molecule-1s-1

Uncertainties are two standard deviations and include the estimated overall uncertainty of the rate constant of the reference reaction.

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