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Author(s):   Balucani, N.; Asvany, O.; Chang, A.H.H.; Lin, S.H.; Lee, Y.T.; Kaiser, R.I.
Title:   Crossed Beam Reaction of Cyano Radicals with Hydrocarbon Molecules. III. Chemical Dynamics of Vinylcyanide (C2H3CN;X1A') Formation From Reaction of CN(X2Σ+) with Ethylene, C2H4(X1Ag)
Journal:   J. Chem. Phys.
Volume:   113
Page(s):   8643 - 8655
Year:   2000
Reference type:   Journal article
Squib:   2000BAL/ASV8643-8655

Reaction:   CN + C2H4 → Other Products + CH2CHCN
Reaction order:   2
Rate expression:   no rate data available
Category:  Experiment
Data type:   Mechanistic information only
Experimental procedure:   Molecular beam
Analytical technique:   Mass spectrometry
Comments:   Crossed-beam study at collision energies of 15.3 and 21.0 kJ/mol. No entrance barrier and reaction proceeds thorugh CH2CH2CN intermediate.

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