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Author(s):   Cedeno, D.L.; Weitz, E.
Title:   Reactions of Fe(CO)3 and Fe(CO)4 with C2Cl4 in the Gas Phase Monitored by Transient Infrared Spectroscopy: Formation of Fe(CO)4(C2Cl4), Fe(CO)3(C2Cl4)2 and Novel Chloride Complexes Resulting from the Oxidative Addition of C2Cl4
Journal:   J. Phys. Chem. A
Volume:   104
Page(s):   8011 - 8026
Year:   2000
Reference type:   Journal article
Squib:   2000CED/WEI8011-8026

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2000CED/WEI8011-8026   C2Cl4 + Fe(CO)3 → Fe(CO)3(C2Cl4)  277 - 310   3.00E-11           3.00E-11  2
  2000CED/WEI8011-8026   Fe(CO)3(C2Cl4) + C2Cl4 → Fe(CO)3(C2Cl4)2  277 - 310   1.90E-11           1.90E-11  2
  2000CED/WEI8011-8026   Fe(CO)3(C2Cl4) + CO → Fe(CO)4(C2Cl4)  297   2.40E-11              2
  2000CED/WEI8011-8026   CO + Fe(CO)3Fe(CO)4  297   2.20E-11              2
  2000CED/WEI8011-8026   C2Cl4 + Fe(CO)4 → Fe(CO)4(C2Cl4)  277 - 310   1.20E-13           1.20E-13  2
  2000CED/WEI8011-8026   Fe(CO)4(C2Cl4) → ClFe(CO)4(C2Cl3)  297 - 315   1.45E12       8.79E04   5.76E-04  1
  2000CED/WEI8011-8026   ClFe(CO)4(C2Cl3) → Products  297 - 315   1210       3.01E04   6.35E-03  1
  2000CED/WEI8011-8026   C2Cl4 + Fe2(CO)8 → Fe2(CO)8(C2Cl4)  297   4.40E-14              2
  2000CED/WEI8011-8026   Fe(CO)3(C2Cl4) + Fe(CO)5 → Products  297   9.70E-12              2

Search returned 9 records.