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Author(s):   Geppert, W.D.; Reignier, D.; Stoecklin, T.; Naulin, C.; Costes, M.; Chastaing, D.; Le Picard, S.D.; Sims, I.R.; Smith, I.WM.
Title:   Comparison of the cross-sections and thermal rate constants for the reactions of C atoms with O2 and NO
Journal:   Phys. Chem. Chem. Phys.
Volume:   2
Page(s):   2873 - 2881
Year:   2000
Reference type:   Journal article
Squib:   2000GEP/REI2873-2881

Reaction:   C(3Pj) + O2CO +
Reaction order:   2
Temperature:   15.00 - 295 K
Pressure:  1.30E9 bar
Rate expression:   4.9x10-11 [±8.0x10-12 cm3/molecule s] (T/298 K)(-0.32±0.08)
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Laval nozzle
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
15.00 1.28E-10
25.00 1.08E-10
50.00 8.68E-11
75.00 7.62E-11
100 6.95E-11
125 6.47E-11
150 6.10E-11
175 5.81E-11
200 5.57E-11
225 5.36E-11
250 5.18E-11
275 5.03E-11
295 4.92E-11