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Accessibility information
Author(s):   Hynes, R.G.; Mackie, J.C.; Masri, A.R.
Title:   A shock tube kinetic study on the reaction of C3F6 and H atoms at high temperatures
Journal:   Proc. Combust. Inst.
Volume:   28
Page(s):   1557 - 1562
Year:   2000
Reference type:   Journal article
Squib:   2000HYN/MAC1557-1562

Reaction:   C2H4 + ·CHF2CH2F2 + C2H3
Reaction order:   2
Temperature:   1250 - 1550 K
Pressure:  16.21 - 18.24 bar
Rate expression:   1.66x10-12 [cm3/molecule s] e-50208 [J/mole]/RT
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Experimental procedure:   Shock tube
Time resolution:   In real time
Analytical technique:   GC-MS

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1250 1.32E-14
1275 1.46E-14
1300 1.60E-14
1325 1.74E-14
1350 1.90E-14
1375 2.06E-14
1400 2.22E-14
1425 2.40E-14
1450 2.58E-14
1475 2.77E-14
1500 2.96E-14
1525 3.17E-14
1550 3.38E-14