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Author(s):   Kukui, A.; Bossoutrot, V.; Laverdet, G.; Le Bras, G.
Title:   Mechanism of the Reaction of CH3SO with NO2 in Relation to Atmospheric Oxidation of Dimethyl Sulfide: Experimental and Theoretical Study
Journal:   J. Phys. Chem. A
Volume:   104
Page(s):   935 - 946
Year:   2000
Reference type:   Journal article
Squib:   2000KUK/BOS935-946

Reaction:   CH3S(O)2 → ·CH3 + SO2
Reaction order:   1
Temperature:   300 K
Pressure:  1.33E-3 - 0.82 bar
Rate expression:   1.0x102 [s-1]
Rate constant is an upper limit.
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure dependent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   Methods used are laser photolysis/laser induced fluorescence and discharge flow mass spectroscopy/laser induced fluorescence. Experimental results are interpreted by and compared with results of ab initio and RRKM calculations.

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