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Author(s):   Li, Q.; Osborne, M.C.; Smith, I.W.M.
Title:   Rate Constants for the Reactions of Cl Atoms with HCOOH and with HOCO Radicals
Journal:   Int J. Chem. Kinet.
Volume:   32
Page(s):   85 - 91
Year:   2000
Reference type:   Journal article
Squib:   2000LI/OSB85-91

Reaction:   HOCO + ClCO2 + HCl
Reaction order:   2
Temperature:   298 K
Pressure:  1.33E-2 bar
Rate expression:   4.8x10-11 [±1.0x10-11 cm3/molecule s]
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   IR absorption
Comments:   Reference indicates that the measurements were conducted at "room temperature". For the purposes of this data base is T=298 K is assumed.

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