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Accessibility information
Author(s):   Manke, G.C., II; Henshaw, T.L.; Madden, T.J.; Hager, G.D.
Title:   Temperature-Dependent Quenching Rate Constants of NF(a1Δ)
Journal:   J. Phys. Chem. A
Volume:   104
Page(s):   1708 - 1714
Year:   2000
Reference type:   Journal article
Squib:   2000MAN/HEN1708-1714

Reaction:   NF(a1Delta) + HCl → Products
Reaction order:   2
Temperature:   300 - 473 K
Pressure:  6.67E-4 - 2.00E-3 bar
Rate expression:   2.0x10-10 [±1.0x10-10 cm3/molecule s] e-27188 [±2079 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   In real time
Analytical technique:   Chemiluminescence
Comments:   Singlet NF generated by:
F + HN3 ?arrow?HF + N3
F + N3 ?arrow?N2 + NF(a1?ELTA?

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 3.69E-15
325 8.54E-15
350 1.75E-14
375 3.27E-14
400 5.63E-14
425 9.11E-14
450 1.40E-13
473 1.99E-13