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Author(s):   McClean, R.E.
Title:   Depletion Kinetics of Chromium Atoms by Sulfur Dioxide
Journal:   J. Phys. Chem. A
Volume:   104
Page(s):   8723 - 8729
Year:   2000
Reference type:   Journal article
Squib:   2000MCC8723-8729

Reaction:   Cr + SO2 → CrSO2
Reaction order:   3
Temperature:   534 K
Pressure:  6.67E-3 - 0.80 bar
Rate expression:   7.5x10-29 [±2.0x10-29 cm6/molecule2 s]
Bath gas:   Ar
Category:  Experiment
Data type:   High or low pressure extrapolation
Pressure dependence:   Rate constant is low pressure limit
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   248 nm photolysis of Cr(CO)6. LIF Detection of Cr at 360.532 nm. Fc=0.56(0.11)

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