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Accessibility information
Author(s):   Sato, K.; Hidaka, Y.
Title:   Shock-tube and modeling study of acetone pyrolysis and oxidation
Journal:   Combust. Flame
Volume:   122
Page(s):   291 - 311
Year:   2000
Reference type:   Journal article
Squib:   2000SAT/HID291-311

Reaction:   (CH3)2CO·CH3 + CH3CO
Reaction order:   1
Temperature:   1050 - 1650 K
Pressure:  1.22 - 3.24 bar
Rate expression:   1.13x1016 [s-1] e-341833 [J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Shock tube
Time resolution:   In real time
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1050 1.12E-1
1100 6.62E-1
1150 3.36E0
1200 1.49E1
1250 5.87E1
1300 2.08E2
1350 6.71E2
1400 1.99E3
1450 5.49E3
1500 1.41E4
1550 3.42E4
1600 7.83E4
1650 1.71E5