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Accessibility information
Author(s):   Sato, K.; Hidaka, Y.
Title:   Shock-tube and modeling study of acetone pyrolysis and oxidation
Journal:   Combust. Flame
Volume:   122
Page(s):   291 - 311
Year:   2000
Reference type:   Journal article
Squib:   2000SAT/HID291-311

Reaction:   (CH3)2CO + H2 + CH3C(O)CH2(·)
Reaction order:   2
Temperature:   1050 - 1650 K
Pressure:  1.22 - 3.24 bar
Rate expression:   3.39x10-12 [cm3/molecule s] (T/298 K)2.00 e-20920 [J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Shock tube
Time resolution:   In real time
Analytical technique:   IR absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1050 3.83E-12
1100 4.69E-12
1150 5.66E-12
1200 6.76E-12
1250 7.97E-12
1300 9.32E-12
1350 1.08E-11
1400 1.24E-11
1450 1.42E-11
1500 1.61E-11
1550 1.81E-11
1600 2.03E-11
1650 2.26E-11