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Accessibility information
Author(s):   Tichenor, L.B.; Graham, J.L.; Yamada, T.; Taylor, P.H.
Title:   Kinetic and Modeling Studies of the Reaction of Hydroxyl Radicals with Tetrachloroethylene
Journal:   J. Phys. Chem. A
Volume:   104
Page(s):   1700 - 1707
Year:   2000
Reference type:   Journal article
Squib:   2000TIC/GRA1700-1707

Reaction:   C2Cl4 + ·OH → Products
Reaction order:   2
Temperature:   296 - 714 K
Pressure:  0.99 bar
Rate expression:   1.6x10-14 [±1.65x10-15 cm3/molecule s] (T/298 K)3.20 e5494 [±454 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   Uncertainties are two standard error. Authors present an Arrhenius fit to their data as well:k(T)= (1.68 ?0.25)E-12 exp{-(764.2 ?79.1)/T}

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
296 1.46E-13
300 1.48E-13
325 1.61E-13
350 1.76E-13
375 1.94E-13
400 2.14E-13
425 2.35E-13
450 2.59E-13
475 2.85E-13
500 3.13E-13
525 3.44E-13
550 3.77E-13
575 4.13E-13
600 4.51E-13
625 4.92E-13
650 5.35E-13
675 5.81E-13
700 6.31E-13
714 6.60E-13