Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Tomas, A.; Caralp, F.; Lesclaux, R.
Title:   Decomposition of the CF3CO radical: Pressure and temperature dependencies of the rate constant
Journal:   Z. Phys. Chem. Inter. J. Res. Phys. Chem. Chem. Phys.
Volume:   214
Page(s):   1349 - 1365
Year:   2000
Reference type:   Journal article
Squib:   2000TOM/CAR1349-1365

Reaction:   CF3C(O)CO + ·CF3
Reaction order:   1
Temperature:   298 - 443 K
Pressure:  1.01 bar
Rate expression:   1.0x1011 [s-1] e-35037 [±4989 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Vis-UV absorption

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
298 7.22E4
300 7.94E4
325 2.34E5
350 5.90E5
375 1.32E6
400 2.66E6
425 4.94E6
443 7.39E6