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Accessibility information
Author(s):   Tomas, A.; Caralp, F.; Lesclaux, R.
Title:   Decomposition of the CF3CO radical: Pressure and temperature dependencies of the rate constant
Journal:   Z. Phys. Chem. Inter. J. Res. Phys. Chem. Chem. Phys.
Volume:   214
Page(s):   1349 - 1365
Year:   2000
Reference type:   Journal article
Squib:   2000TOM/CAR1349-1365

Reaction:   CF3C(O)CO + ·CF3
Reaction order:   1
Temperature:   220 - 450 K
Pressure:  1.33E-3 - 1.01 bar
Rate expression:   1.45x1014 [s-1] e-48872 [J/mole]/RT
Category:  Theory
Data type:   RRK(M) extrapolation
Pressure dependence:   Rate constant is high pressure limit

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
220 3.61E2
225 6.54E2
250 8.92E3
275 7.56E4
300 4.49E5
325 2.03E6
350 7.37E6
375 2.26E7
400 6.02E7
425 1.43E8
450 3.08E8