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Accessibility information
Author(s):   Tomas, A.; Villenave, E.; Lesclaux, R.
Title:   Kinetics of the (CH3)2CHCO and (CH3)3CCO Radical Decomposition: Temperature and Pressure Dependences
Journal:   Phys. Chem. Chem. Phys.
Volume:   2
Page(s):   1165 - 1174
Year:   2000
Reference type:   Journal article
Squib:   2000TOM/VIL1165-1174

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2000TOM/VIL1165-1174   (CH3)2CHC=O → Propyl Radical + CO  413 - 503   3.80E12       4.96E04      1
  2000TOM/VIL1165-1174   (CH3)3CC(O)· → Products + CO  323 - 453   1.65E12       4.05E04      1
  2000TOM/VIL1165-1174   (CH3)2CHC=O → Propyl Radical + CO  403 - 503   3.30E14       5.94E04      1
  2000TOM/VIL1165-1174   (CH3)3CC(O)· → Products + CO  323 - 453   1.10E14       5.06E04      1

Search returned 4 records.